一种生成邻醌甲基化物的温和阴离子方法：邻位官能化酚的简便制备
A mild anionic method for generating o-quinone methides: facile preparations of ortho-functionalized phenols.
作者信息
Jones R M, Van De Water R W, Lindsey C C, Hoarau C, Ung T, Pettus T R
机构信息
Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106-9510, USA.
出版信息
J Org Chem. 2001 May 18;66(10):3435-41. doi: 10.1021/jo001752e.
PMID:11348127
Abstract
A low-temperature method for generating o-quinone methides is described which permits facile introduction of assorted R substituents onto the aryl ring system at low temperature. The method is useful for the efficient preparation of ortho-ring-alkylated phenols.
摘要
描述了一种生成邻醌甲基化物的低温方法，该方法允许在低温下将各种R取代基轻松引入芳环体系。该方法可用于高效制备邻环烷基化苯酚。
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