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1
Applications of ortho-quinone methide intermediates in catalysis and asymmetric synthesis.芳氧甲叉中间体在催化和不对称合成中的应用。
J Org Chem. 2011 Nov 18;76(22):9210-5. doi: 10.1021/jo201789k. Epub 2011 Oct 19.
2
Enantio- and diastereoselective access to distant stereocenters embedded within tetrahydroxanthenes: utilizing ortho-quinone methides as reactive intermediates in asymmetric Brønsted acid catalysis.对映选择性和非对映选择性地构建四氢蒽酮中远程手性中心：利用邻醌甲醚作为不对称布朗斯特酸催化中的反应中间体。
Angew Chem Int Ed Engl. 2014 Nov 24;53(48):13258-63. doi: 10.1002/anie.201406587. Epub 2014 Oct 6.
3
Aza-Ortho-Quinone Methides as Reactive Intermediates: Generation and Utility in Contemporary Asymmetric Synthesis.氮杂-Ortho-醌甲烯作为反应中间体：在当代不对称合成中的生成与应用。
Chemistry. 2022 Aug 16;28(46):e202201112. doi: 10.1002/chem.202201112. Epub 2022 Jun 27.
4
Enantioselective [4 + 1] cycloaddition of ortho-quinone methides and bromomalonates under phase-transfer catalysis.相转移催化下邻醌甲基化物与溴代丙二酸酯的对映选择性[4 + 1]环加成反应
Org Biomol Chem. 2017 May 3;15(17):3670-3673. doi: 10.1039/c7ob00484b.
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ortho-Quinone methides in natural product synthesis.在天然产物合成中，邻醌甲川化合物。
Chemistry. 2012 Jul 23;18(30):9160-73. doi: 10.1002/chem.201200619. Epub 2012 Jun 15.
6
Asymmetric cycloadditions of o-quinone methides employing chiral ammonium fluoride precatalysts.使用手性氟化铵预催化剂的邻醌甲基化物的不对称环加成反应。
Org Lett. 2008 Nov 6;10(21):4951-3. doi: 10.1021/ol802029e. Epub 2008 Oct 14.
7
Palladium-catalyzed enantioselective addition of two distinct nucleophiles across alkenes capable of quinone methide formation.钯催化的烯丙基取代反应，可用于形成醌甲基化物的烯烃与两种不同亲核试剂的对映选择性加成。
J Am Chem Soc. 2009 Dec 2;131(47):17074-5. doi: 10.1021/ja909030c.
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Nucleophilic capture of the imino-quinone methide type intermediates generated from 2-aminothiazol-5-yl carbinols.亲核捕获 2-氨基噻唑-5-基甲醇生成的亚氨基-醌甲亚胺型中间体。
Org Lett. 2009 Nov 19;11(22):5154-7. doi: 10.1021/ol902023g.
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Catalytic Asymmetric 1,6-Conjugate Addition of para-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters.对醌甲基化物的催化不对称 1,6-共轭加成：全碳季碳中心的形成。
Angew Chem Int Ed Engl. 2015 Nov 9;54(46):13711-4. doi: 10.1002/anie.201506701. Epub 2015 Sep 25.
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Stereoselective Synthesis of Atropisomeric Acridinium Salts by the Catalyst-Controlled Cyclization of ortho-Quinone Methide Iminiums.通过邻醌甲亚胺鎓的催化剂控制环化反应进行手性吖啶鎓盐的立体选择性合成。
Angew Chem Int Ed Engl. 2022 May 2;61(19):e202201424. doi: 10.1002/anie.202201424. Epub 2022 Feb 25.
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1
A Palladium-Catalyzed Cascade Double Annulation Strategy for Modular Access to Dihydrocyclopenta[]chromenes.一种用于模块化合成二氢环戊并[]色烯的钯催化串联双环化策略。
Org Lett. 2025 Aug 8;27(31):8405-8410. doi: 10.1021/acs.orglett.5c01856. Epub 2025 Jul 28.
2
Tailored amination enables switchable synthesis of α- and γ-amino acid derivatives from extended quinone methides.定制胺化反应能够从扩展的醌甲基化物中实现α-和γ-氨基酸衍生物的可切换合成。
Nat Commun. 2025 Jul 1;16(1):5683. doi: 10.1038/s41467-025-60749-7.
3
Synthesis of fused-ring systems and diarylmethane flavonoids -quinone methide intermediates.稠环系统与二芳基甲烷类黄酮 - 醌甲基化物中间体的合成。
RSC Adv. 2025 Jan 29;15(4):2912-2929. doi: 10.1039/d4ra08704f. eCollection 2025 Jan 23.
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Copper(I)-Catalyzed Formal [4 + 2] Cyclocondensation of -Hydroxybenzyl Alcohol, Aromatic Terminal Alkynes, and Sulfonyl Azides: An Alternative Approach to 2-Sulfonyliminocoumarins.铜（I）催化的α-羟基苄醇、芳族末端炔烃和磺酰叠氮化物的形式[4 + 2]环缩合反应：一种合成2-磺酰亚氨基香豆素的替代方法。
Molecules. 2024 Jul 22;29(14):3426. doi: 10.3390/molecules29143426.
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Synthesis of Functionalized Tetrahydroquinoline Containing Indole Scaffold via Chemoselective Annulation of Aza--quinone Methide Precursor.通过氮杂-醌甲基化物前体的化学选择性环化合成含吲哚骨架的功能化四氢喹啉
ACS Omega. 2023 Jun 13;8(25):22352-22360. doi: 10.1021/acsomega.2c07036. eCollection 2023 Jun 27.
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Construction of azaheterocycles via Pd-catalyzed migratory cycloannulation reaction of unactivated alkenes.钯催化的非活化烯烃的迁移环化反应构建氮杂杂环。
Nat Commun. 2022 Aug 27;13(1):5059. doi: 10.1038/s41467-022-32726-x.
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Asymmetric synthesis of polysubstituted chiral chromans an organocatalytic oxa-Michael-nitro-Michael domino reaction.多取代手性色满的不对称合成——有机催化的氧杂-迈克尔-硝基-迈克尔串联反应
RSC Adv. 2018 Jan 17;8(6):3095-3098. doi: 10.1039/c7ra13525d. eCollection 2018 Jan 12.
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Diastereoselective synthesis of CF-dihydrobenzofurans by [4+1] annulation of -generated CF--quinone methides and sulfur ylides.通过由生成的CF-醌甲基化物和硫叶立德进行[4+1]环化反应实现CF-二氢苯并呋喃的非对映选择性合成。
RSC Adv. 2020 Oct 20;10(63):38588-38591. doi: 10.1039/d0ra08289a. eCollection 2020 Oct 15.
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A formal intermolecular [4 + 1] cycloaddition reaction of 3-chlorooxindole and -quinone methides: a facile synthesis of spirocyclic oxindole scaffolds.3-氯氧化吲哚与醌甲基化物的正式分子间[4 + 1]环加成反应：螺环氧化吲哚骨架的简便合成
RSC Adv. 2021 May 24;11(30):18576-18579. doi: 10.1039/d1ra01086g. eCollection 2021 May 19.
10
Photogeneration of quinone methide from adamantylphenol in an ultrafast non-adiabatic dehydration reaction.金刚烷基苯酚在超快非绝热脱水反应中生成醌甲醚。
Phys Chem Chem Phys. 2022 Feb 16;24(7):4384-4393. doi: 10.1039/d1cp05690e.
本文引用的文献
1
Palladium-catalyzed hydrofunctionalization of vinyl phenol derivatives with heteroaromatics.钯催化的乙烯基酚衍生物与杂芳烃的氢官能化反应。
Org Lett. 2011 May 20;13(10):2774-7. doi: 10.1021/ol200913r. Epub 2011 Apr 21.
2
Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reaction.推进对映选择性钯催化烯烃双官能化反应的机理理解。
J Am Chem Soc. 2010 Dec 15;132(49):17471-82. doi: 10.1021/ja108106h. Epub 2010 Nov 17.
3
Dynamic cross-linking is retained in duplex DNA after multiple exchange of strands.在多次链交换后，双链DNA中仍保留动态交联。
Angew Chem Int Ed Engl. 2010 Aug 9;49(34):5957-60. doi: 10.1002/anie.201001597.
4
Synthesis and preliminary biological studies of 3-substituted indoles accessed by a palladium-catalyzed enantioselective alkene difunctionalization reaction.通过钯催化的烯烃双官能化反应合成并初步研究了 3-取代吲哚。
J Am Chem Soc. 2010 Jun 16;132(23):7870-1. doi: 10.1021/ja103472a.
5
Palladium-catalyzed enantioselective addition of two distinct nucleophiles across alkenes capable of quinone methide formation.钯催化的烯丙基取代反应，可用于形成醌甲基化物的烯烃与两种不同亲核试剂的对映选择性加成。
J Am Chem Soc. 2009 Dec 2;131(47):17074-5. doi: 10.1021/ja909030c.
6
Quinone methides tethered to naphthalene diimides as selective G-quadruplex alkylating agents.醌甲基化物与萘二酰亚胺连接作为选择性 G-四链体烷化剂。
J Am Chem Soc. 2009 Sep 16;131(36):13132-41. doi: 10.1021/ja904876q.
7
Asymmetric cycloadditions of o-quinone methides employing chiral ammonium fluoride precatalysts.使用手性氟化铵预催化剂的邻醌甲基化物的不对称环加成反应。
Org Lett. 2008 Nov 6;10(21):4951-3. doi: 10.1021/ol802029e. Epub 2008 Oct 14.
8
Photolabile protection of alcohols, phenols, and carboxylic acids with 3-hydroxy-2-naphthalenemethanol.用3-羟基-2-萘甲醇对醇类、酚类和羧酸进行光不稳定保护。
J Org Chem. 2008 Oct 3;73(19):7611-5. doi: 10.1021/jo801302m. Epub 2008 Sep 10.
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BINOL-amino acid conjugates as triggerable carriers of DNA-targeted potent photocytotoxic agents.联萘酚-氨基酸缀合物作为可触发的DNA靶向强效光细胞毒性剂载体。
J Med Chem. 2007 Dec 27;50(26):6570-9. doi: 10.1021/jm070828x. Epub 2007 Nov 30.
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Palladium(II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: a pronounced effect of copper additives on enantioselectivity.钯（II）催化的2-丙烯基苯酚对映选择性有氧二烷氧基化反应：铜添加剂对映选择性的显著影响。
J Am Chem Soc. 2007 Mar 21;129(11):3076-7. doi: 10.1021/ja070263u. Epub 2007 Feb 14.
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