有机卤化物与醛的电化学偶联反应，由铬盐和镍盐催化，即野崎-桧山-岸反应。
An electrochemical coupling of organic halide with aldehydes, catalytic in chromium and nickel salts. the Nozaki-Hiyama-Kishi reaction.
作者信息
Durandetti M, Nédélec J Y, Périchon J
机构信息
Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, UMR 7582, Université Paris 12, 2 rue Henri-Dunant 94320 Thiais, France.
出版信息
Org Lett. 2001 Jun 28;3(13):2073-6. doi: 10.1021/ol016033g.
[reaction: see text] Electrochemical arylation of arenecarboxaldehydes using an iron sacrificial anode in the presence of chromium and nickel catalysts afforded the corresponding arylated secondary alcohols in moderate to good yields. The chromium and nickel salts as catalysts are obtained by oxidation of a stainless steel rod during a preelectrolysis in 7% and 3%, respectively. The process was also applied to the addition of vinyl halide, allyl acetate, or alpha-chloroester to aromatic aldehydes.
[反应：见正文] 在铬和镍催化剂存在下，使用铁牺牲阳极对芳基甲醛进行电化学芳基化反应，以中等至良好的产率得到相应的芳基化仲醇。作为催化剂的铬盐和镍盐分别通过在7%和3%的预电解过程中不锈钢棒的氧化而获得。该方法也适用于卤化乙烯、乙酸烯丙酯或α-氯酯与芳香醛的加成反应。
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