MacDiarmid Alan G.
Department of Chemistry University of Pennsylvania Philadelphia, PA 19104-6323 (USA).
Angew Chem Int Ed Engl. 2001 Jul 16;40(14):2581-2590.
Since the initial discovery in 1977, that polyacetylene (CH)(x), now commonly known as the prototype conducting polymer, could be p- or n-doped either chemically or electrochemically to the metallic state, the development of the field of conducting polymers has continued to accelerate at an unexpectedly rapid rate and a variety of other conducting polymers and their derivatives have been discovered. Other types of doping are also possible, such as "photo-doping" and "charge-injection doping" in which no counter dopant ion is involved. One exciting challenge is the development of low-cost disposable plastic/paper electronic devices. Conventional inorganic conductors, such as metals, and semiconductors, such as silicon, commonly require multiple etching and lithographic steps in fabricating them for use in electronic devices. The number of processing and etching steps involved limits the minimum price. On the other hand, conducting polymers combine many advantages of plastics, for example, flexibility and processing from solution, with the additional advantage of conductivity in the metallic or semiconducting regimes; however, the lack of simple methods to obtain inexpensive conductive polymer shapes/patterns limit many applications. Herein is described a novel, simple, and cheap method to prepare patterns of conducting polymers by a process which we term, "Line Patterning".
自1977年首次发现聚乙炔(CH)(x)(现通常被称为原型导电聚合物)可以通过化学或电化学方式进行p型或n型掺杂至金属态以来,导电聚合物领域的发展一直以意想不到的快速速度持续加速,并且已经发现了多种其他导电聚合物及其衍生物。还可能存在其他类型的掺杂,例如“光掺杂”和“电荷注入掺杂”,其中不涉及反掺杂离子。一个令人兴奋的挑战是开发低成本的一次性塑料/纸质电子设备。传统的无机导体,如金属,以及半导体,如硅,在制造用于电子设备时通常需要多个蚀刻和光刻步骤。所涉及的加工和蚀刻步骤数量限制了最低价格。另一方面,导电聚合物结合了塑料的许多优点,例如柔韧性和可从溶液中加工,还具有在金属或半导体状态下导电的额外优点;然而,缺乏获得廉价导电聚合物形状/图案的简单方法限制了许多应用。本文描述了一种新颖、简单且廉价的方法,通过我们称为“线条图案化”的过程来制备导电聚合物图案。