Janssen A J, Ruitenberg R, Buisman C J
Paques BV, Balk, The Netherlands.
Water Sci Technol. 2001;44(8):85-90.
The emission of sulphur compounds into the environment is undesirable because of their acidifying characteristics. The processing of sulphidic ores, oil refining and sulphuric acid production are major sources of SO2 emissions. Hydrogen sulphide is emitted into the environment as dissolved sulphide in wastewater or as H2S in natural gas, biogas, syngas or refinery gases. Waste streams containing sulphate are generated by many industries, including mining, metallurgical, pulp and paper and petrochemical industries. Applying process technologies that rely on the biological sulphur cycle can prevent environmental pollution. In nature sulphur compounds may cycle through a series of oxidation states (-2, 0, +2, +4, +6). Bacteria of a wide range of genera gain metabolic energy from either oxidising or reducing sulphur compounds. Paques B.V. develops and constructs reactor systems to remove sulphur compounds from aqueous and gaseous streams by utilising naturally occurring bacteria from the sulphur cycle. Due to the presence of sulphide, heavy metal removal is also achieved with very high removal efficiencies. Ten years of extensive laboratory and pilot plant research has, to date, resulted in the construction of over 30 full-scale installations. This paper presents key processes from the sulphur cycle and discusses recent developments about their application in industry.
由于含硫化合物具有酸化特性,向环境中排放此类化合物是不可取的。硫化矿石加工、炼油和硫酸生产是二氧化硫排放的主要来源。硫化氢以废水中溶解的硫化物形式或在天然气、沼气、合成气或炼厂气中以硫化氢形式排放到环境中。包括采矿、冶金、造纸和石油化工等许多行业都会产生含硫酸盐的废物流。应用依赖生物硫循环的工艺技术可以防止环境污染。在自然界中,硫化合物可能会经历一系列氧化态(-2、0、+2、+4、+6)循环。多种属的细菌通过氧化或还原硫化合物获取代谢能量。帕克斯有限公司开发并构建反应器系统,利用硫循环中的天然细菌从水流和气态流中去除硫化合物。由于硫化物的存在,重金属去除效率也非常高。迄今为止,经过十年广泛的实验室和中试工厂研究,已建成30多个全规模装置。本文介绍了硫循环中的关键过程,并讨论了它们在工业应用中的最新进展。