Ouyang Min, Huang Jin-Lin, Lieber Charles M
Department of Chemistry and Chemical Biology and Division of Engineering and Applied Science, Harvard University, Cambridge, Massachusetts 02138, USA.
Acc Chem Res. 2002 Dec;35(12):1018-25. doi: 10.1021/ar0101685.
Recent scanning tunneling microscopy studies of the intrinsic electronic properties of single-walled carbon nanotubes (SWNTs) are overviewed in this Account. A brief theoretical treatment of the electronic properties of SWNTs is developed, and then the effects of finite curvature and broken symmetry on electronic properties, the unique one-dimensional energy dispersion in nanotubes, the interaction between local spins and carriers in metallic nanotubes systems, and the atomic structure and electronic properties of intramolecular junctions are described. The implications of these studies for understanding fundamental one-dimensional physics and future nanotube device applications are also discussed.
本综述介绍了近期对单壁碳纳米管(SWNTs)本征电子性质的扫描隧道显微镜研究。首先对SWNTs的电子性质进行了简要的理论探讨,然后描述了有限曲率和对称性破缺对电子性质的影响、纳米管中独特的一维能量色散、金属纳米管系统中局域自旋与载流子之间的相互作用,以及分子内结的原子结构和电子性质。还讨论了这些研究对理解基本一维物理和未来纳米管器件应用的意义。