McKenzie Richard L, Björn Lars Olof, Bais Alkiviadis, Ilyasad Mohammad
National Institute of Water and Atmospheric Research, NIWA Lauder, PB 50061 Omakau, Central Otago, New Zealand.
Photochem Photobiol Sci. 2003 Jan;2(1):5-15. doi: 10.1039/b211155c.
Since publication of the 1998 UNEP Assessment, there has been continued rapid expansion of the literature on UV-B radiation. Many measurements have demonstrated the inverse relationship between column ozone amount and UV radiation, and in a few cases long-term increases due to ozone decreases have been identified. The quantity, quality and availability of ground-based UV measurements relevant to assessing the environmental impacts of ozone changes continue to improve. Recent studies have contributed to delineating regional and temporal differences due to aerosols, clouds, and ozone. Improvements in radiative transfer modelling capability now enable more accurate characterization of clouds, snow-cover, and topographical effects. A standardized scale for reporting UV to the public has gained wide acceptance. There has been increased use of satellite data to estimate geographic variability and trends in UV. Progress has been made in assessing the utility of satellite retrievals of UV radiation by comparison with measurements at the Earth's surface. Global climatologies of UV radiation are now available on the Internet. Anthropogenic aerosols play a more important role in attenuating UV irradiances than has been assumed previously, and this will have implications for the accuracy of UV retrievals from satellite data. Progress has been made inferring historical levels of UV radiation using measurements of ozone (from satellites or from ground-based networks) in conjunction with measurements of total solar radiation obtained from extensive meteorological networks. We cannot yet be sure whether global ozone has reached a minimum. Atmospheric chlorine concentrations are beginning to decrease. However, bromine concentrations are still increasing. While these halogen concentrations remain high, the ozone layer remains vulnerable to further depletion from events such as volcanic eruptions that inject material into the stratosphere. Interactions between global warming and ozone depletion could delay ozone recovery by several years, and this topic remains an area of intense research interest. Future changes in greenhouse gases will affect the future evolution of ozone through chemical, radiative, and dynamic processes In this highly coupled system, an evaluation of the relative importance of these processes is difficult: studies are ongoing. A reliable assessment of these effects on total column ozone is limited by uncertainties in lower stratospheric response to these changes. At several sites, changes in UV differ from those expected from ozone changes alone, possibly as a result of long-term changes in aerosols, snow cover, or clouds. This indicates a possible interaction between climate change and UV radiation. Cloud reflectance measured by satellite has shown a long-term increase at some locations, especially in the Antarctic region, but also in Central Europe, which would tend to reduce the UV radiation. Even with the expected decreases in atmospheric chlorine, it will be several years before the beginning of an ozone recovery can be unambiguously identified at individual locations. Because UV-B is more variable than ozone, any identification of its recovery would be further delayed.
自1998年联合国环境规划署(UNEP)评估报告发布以来,关于紫外线B辐射的文献持续迅速增加。许多测量结果表明了大气臭氧总量与紫外线辐射之间的反比关系,并且在少数情况下,已经确定了由于臭氧减少导致的紫外线长期增加。与评估臭氧变化对环境影响相关的地面紫外线测量的数量、质量和可得性持续改善。最近的研究有助于描绘出由于气溶胶、云层和臭氧导致的区域和时间差异。辐射传输建模能力的提高现在能够更准确地表征云层、积雪和地形的影响。一种向公众报告紫外线的标准化尺度已获得广泛认可。利用卫星数据估计紫外线的地理变异性和趋势的情况有所增加。通过与地面测量结果进行比较,在评估卫星反演紫外线辐射的效用方面取得了进展。现在可以在互联网上获取全球紫外线辐射气候学数据。人为气溶胶在减弱紫外线辐照度方面所起的作用比以前所认为的更为重要,这将对从卫星数据反演紫外线的准确性产生影响。利用(来自卫星或地面网络的)臭氧测量数据以及从广泛的气象网络获得的总太阳辐射测量数据,在推断历史紫外线辐射水平方面取得了进展。我们尚不能确定全球臭氧是否已达到最低值。大气氯浓度开始下降。然而,溴浓度仍在上升。在这些卤素浓度仍然很高的情况下,臭氧层仍然容易受到诸如向平流层注入物质的火山喷发等事件导致的进一步损耗。全球变暖和臭氧消耗之间的相互作用可能会使臭氧恢复推迟数年,并且这个话题仍然是一个研究热点领域。未来温室气体的变化将通过化学、辐射和动力过程影响臭氧的未来演变。在这个高度耦合的系统中,评估这些过程的相对重要性很困难:相关研究正在进行中。对这些对大气臭氧总量的影响进行可靠评估受到平流层下部对这些变化响应的不确定性的限制。在几个地点,紫外线的变化与仅由臭氧变化所预期的情况不同,这可能是由于气溶胶、积雪或云层的长期变化所致。这表明气候变化与紫外线辐射之间可能存在相互作用。卫星测量的云层反射率在一些地点,特别是在南极地区,但也在中欧,显示出长期增加,这往往会减少紫外线辐射。即使大气氯预期会减少,在各个地点明确确定臭氧开始恢复之前仍需数年时间。由于紫外线B比臭氧更具变化性,其恢复的任何确定都将进一步推迟。