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随机单分散泡沫的结构

Structure of random monodisperse foam.

作者信息

Kraynik Andrew M, Reinelt Douglas A, van Swol Frank

机构信息

Department 9114 MS0834, Sandia National Laboratories, Albuquerque, New Mexico 87185-0834, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2003 Mar;67(3 Pt 1):031403. doi: 10.1103/PhysRevE.67.031403. Epub 2003 Mar 21.

DOI:10.1103/PhysRevE.67.031403
PMID:12689063
Abstract

The Surface Evolver was used to calculate the equilibrium microstructure of random monodisperse soap froth, starting from Voronoi partitions of randomly packed spheres. The sphere packing has a strong influence on foam properties, such as E (surface free energy) and (average number of faces per cell). This means that random foams composed of equal-volume cells come in a range of structures with different topological and geometric properties. Annealing-subjecting relaxed foams to large-deformation, tension-compression cycles-provokes topological transitions that can further reduce E and . All of the foams have <or=14. The topological statistics and census of cell types for fully annealed foams are in excellent agreement with experiments by Matzke. Geometric properties related to surface area, edge length, and stress are evaluated for the foams and their individual cells. Simple models based on regular polygons predict trends for the edge length of individual cells and the area of individual faces. Graphs of surface area vs shape anisotropy for the cells reflect the geometrical frustration in random monodisperse foam, which is epitomized by pentagonal dodecahedra: they have low surface area but do not pack to fill space.

摘要

从随机堆积球体的沃罗诺伊分割开始,使用表面演化器计算随机单分散肥皂泡的平衡微观结构。球体堆积对泡沫特性有很大影响,例如E(表面自由能)和(每个单元的平均面数)。这意味着由等体积单元组成的随机泡沫具有一系列具有不同拓扑和几何特性的结构。退火——使松弛泡沫经历大变形、拉伸-压缩循环——会引发拓扑转变,这可以进一步降低E和。所有泡沫的≤14。完全退火泡沫的拓扑统计和单元类型普查与Matzke的实验结果非常吻合。对泡沫及其单个单元的与表面积、边长和应力相关的几何特性进行了评估。基于正多边形的简单模型预测了单个单元的边长和单个面的面积趋势。单元的表面积与形状各向异性的关系图反映了随机单分散泡沫中的几何挫折,以五角十二面体为代表:它们的表面积低,但不能填充空间。

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