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烟熏海产品中的多环芳烃、多氯联苯、氯化农药(滴滴涕)、六氯环己烷和六氯苯残留

Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, chlorinated pesticides (DDTs), hexachlorocyclohexane, and hexachlorobenzene residues in smoked seafood.

作者信息

Storelli M M, Stuffler R Giacominelli, Marcotrigianoi G O

机构信息

Pharmacological-Biological Department, Chemistry and Biochemistry Section, Veterinary Medicine Faculty, University of Bari, Strada Provinciale per Casamassima Km 3, 70010 Valenzano (Ba), Italy.

出版信息

J Food Prot. 2003 Jun;66(6):1095-9. doi: 10.4315/0362-028x-66.6.1095.

Abstract

Smoked seafoods were screened for the presence of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and other organochlorine compounds. Total PAH concentrations ranged from 46.5 ng/g (wet weight) for smoked swordfish to 124.0 ng/g (wet weight) for smoked herring. Among the carcinogenic PAHs, benzo(a)pyrene ranged from undetectable levels for several smoked fish to 0.7 ng/g for Scottish salmon, dibenzo(ah)anthracene was not present in any of the samples analyzed, and benzo(a)anthracene was found in all samples and at particularly high levels in salmon (23.2 ng/g). Benzo(a)pyrene concentrations were below the tolerance limit for all samples. PCB concentrations for the different samples ranged from 2 to 30 ng/g. Chlorinated pesticides (DDTs: p,p'-DDE, p,p'-DDT, o,p'-DDT, p,p'-DDD, and o,p'-DDD) were detected at levels ranging from 0.2 ng/g (wet weight) in bluefin tuna to 17.5 ng/g (wet weight) in salmon. Hexachlorocyclohexane isomers (alphaHCH + betaHCH + gammaHCH) were present in higher amounts in eels (6.5 ng/g) than in the other smoked fish. For 40% of the samples, PCB concentrations exceeded the limit fixed by the European Union, while pesticide levels were below the maximum acceptable limit proposed by the Food and Agriculture Organization.

摘要

对烟熏海产品进行了多环芳烃(PAHs)、多氯联苯(PCBs)及其他有机氯化合物的检测。总PAH浓度范围为:烟熏旗鱼46.5纳克/克(湿重)至烟熏鲱鱼124.0纳克/克(湿重)。在致癌PAHs中,几种烟熏鱼中苯并(a)芘未检出,苏格兰鲑鱼中为0.7纳克/克;所分析的所有样品中均未检测到二苯并(ah)蒽;所有样品中均检测到苯并(a)蒽,鲑鱼中含量特别高(23.2纳克/克)。所有样品中苯并(a)芘浓度均低于耐受限度。不同样品的PCB浓度范围为2至30纳克/克。检测到的氯代农药(滴滴涕:p,p'-DDE、p,p'-DDT、o,p'-DDT、p,p'-DDD和o,p'-DDD)水平范围为:蓝鳍金枪鱼中0.2纳克/克(湿重)至鲑鱼中17.5纳克/克(湿重)。六氯环己烷异构体(α-HCH + β-HCH + γ-HCH)在鳗鱼中的含量(6.5纳克/克)高于其他烟熏鱼。40%的样品中,PCB浓度超过了欧盟规定的限值,而农药水平低于联合国粮食及农业组织提议的最大可接受限值。

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