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波斯尼亚和黑塞哥维那传统烟熏和工业烟熏猪肉制品中的有机氯农药和多氯联苯

Organochlorine Pesticides and PCBs in Traditionally and Industrially Smoked Pork Meat Products from Bosnia and Herzegovina.

作者信息

Kartalović Brankica, Mastanjević Krešimir, Novakov Nikolina, Vranešević Jelena, Ljubojević Pelić Dragana, Puljić Leona, Habschied Kristina

机构信息

Scientific Veterinary Institute Novi Sad, Rumenački put 20, 21000 Novi Sad, Serbia.

Faculty of Food technology, Josip Juraj Strossmayer University of Osijek, F. Kuhača 20, 31000 Osijek, Croatia.

出版信息

Foods. 2020 Jan 17;9(1):97. doi: 10.3390/foods9010097.

Abstract

The aim of this study was to determine the concentration of 19 organochlorine pesticides (OCPs): (hexachlorocyclohexane (α-HCH, β-HCH, δ-HCH), lindane, aldrin, heptachlor, heptachlor epoxide, -chlordane, -chlordane, endosulfane I, endosulfane II, endosulfane sulfate, dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethylene (DDE), dieldrin, endrin, dichlorodiphenyldichloroethane (DDD), methoxychlor and endrin ketone and 6 polychlorinated biphenyls (PCBs) (PCB 28, PCB 52, PCB 101, PCB 153, PCB 138 and PCB 180). The samples were taken from pancetta, dry pork neck (budiola), pork tenderloin and sausages produced in Rakitno (Bosnia and Herzegovina), smoked in both a traditional smokehouse and in an industrial chamber. Instrumental analysis was performed using gas chromatography-mass spectrometry (GC-MS). The reliability of the results, i.e., quality control is ensured by standard laboratory practice, which involves participation in proficiency test, the use of blank samples, reference materials and implementation of recommendations given by the relevant international organizations. The concentrations of α-HCH, lindane, PCB 28, PCB 52 and PCB 153 were detected and quantified. The concentrations of OCPs and PCBs did not significantly vary depending on product type and the conditions of production. All the examined samples were for human consumption.

摘要

本研究的目的是测定19种有机氯农药(OCPs)的浓度:(六氯环己烷(α-六氯环己烷、β-六氯环己烷、δ-六氯环己烷)、林丹、艾氏剂、七氯、七氯环氧化物、α-氯丹、γ-氯丹、硫丹I、硫丹II、硫丹硫酸盐、二氯二苯三氯乙烷(DDT)、二氯二苯二氯乙烯(DDE)、狄氏剂、异狄氏剂、二氯二苯二氯乙烷(DDD)、甲氧滴滴涕和异狄氏剂酮)以及6种多氯联苯(PCBs)(PCB 28、PCB 52、PCB 101、PCB 153、PCB 138和PCB 180)。样本取自拉基特诺(波斯尼亚和黑塞哥维那)生产的意大利培根、干猪颈肉(布迪奥拉)、猪里脊肉和香肠,这些产品在传统烟熏房和工业烟熏室中进行烟熏。使用气相色谱-质谱联用仪(GC-MS)进行仪器分析。通过标准实验室操作确保结果的可靠性,即质量控制,这包括参加能力验证测试、使用空白样品、参考物质以及执行相关国际组织给出的建议。检测并定量了α-六氯环己烷、林丹、PCB 28、PCB 52和PCB 153的浓度。OCPs和PCBs的浓度并未因产品类型和生产条件而有显著差异。所有检测样本均供人类食用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b84f/7022388/083ce1cf293d/foods-09-00097-g001.jpg

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