钯催化下烯烃在氧气氛围中通过碳-碳键断裂进行氧化炔基化反应。
Palladium-catalyzed oxidative alkynylation of alkenes via C-C bond bleavage under oxygen atmosphere.
作者信息
Nishimura Takahiro, Araki Hitoshi, Maeda Yasunari, Uemura Sakae
机构信息
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
出版信息
Org Lett. 2003 Aug 21;5(17):2997-9. doi: 10.1021/ol0348405.
PMID:12916965
Abstract
Palladium-catalyzed oxidative alkynylation of alkenes using tert-propargylic alcohols as alkynylation reagents via C-C bond cleavage under an oxygen atmosphere affords the corresponding ene-yne compounds.
摘要
在氧气氛围下，以叔炔丙醇作为炔基化试剂，通过碳 - 碳键裂解，钯催化烯烃的氧化炔基化反应可得到相应的烯炔化合物。
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