用过氧化氢水溶液进行绿色氧化。
Green oxidation with aqueous hydrogen peroxide.
作者信息
Noyori Ryoji, Aoki Masao, Sato Kazuhiko
机构信息
Department of Chemistry and Research Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
出版信息
Chem Commun (Camb). 2003 Aug 21(16):1977-86. doi: 10.1039/b303160h.
DOI:10.1039/b303160h
PMID:12934880
Abstract
Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally satisfying manner.
摘要
当与钨酸盐配合物和作为酸性相转移催化剂的硫酸氢季铵盐结合使用时，过氧化氢水溶液是一种理想的氧化剂。它能在无有机溶剂和卤化物的条件下，以经济、技术和环境方面都令人满意的方式氧化醇类、烯烃和硫化物。
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