金属介导的[2 + 2 + 2]环加成反应构建吡啶环 - Suppr

Construction of pyridine rings by metal-mediated [2 + 2 + 2] cycloaddition.

作者信息

Varela Jesús A, Saá Carlos

机构信息

Departamento de Química Orgánica y Unidad Asociada al CSIC, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain.

出版信息

Chem Rev. 2003 Sep;103(9):3787-801. doi: 10.1021/cr030677f.

DOI:10.1021/cr030677f

PMID:12964884

Abstract

摘要

相似文献

Construction of pyridine rings by metal-mediated [2 + 2 + 2] cycloaddition.金属介导的[2 + 2 + 2]环加成反应构建吡啶环

Chem Rev. 2003 Sep;103(9):3787-801. doi: 10.1021/cr030677f.

The fascinating construction of pyridine ring systems by transition metal-catalysed [2 + 2 + 2] cycloaddition reactions.过渡金属催化的[2 + 2 + 2]环加成反应构建吡啶环系统的迷人之处。

Chem Soc Rev. 2007 Jul;36(7):1085-94. doi: 10.1039/b607877j. Epub 2007 May 2.

Catalytic "active-metal" template synthesis of [2]rotaxanes, [3]rotaxanes, and molecular shuttles, and some observations on the mechanism of the cu(i)-catalyzed azide-alkyne 1,3-cycloaddition.[2]轮烷、[3]轮烷和分子穿梭体的催化“活性金属”模板合成，以及关于铜（I）催化的叠氮化物-炔烃1,3-环加成反应机理的一些观察结果。

J Am Chem Soc. 2007 Oct 3;129(39):11950-63. doi: 10.1021/ja073513f. Epub 2007 Sep 11.

1,3-Dipolar cycloaddition of alkynes to azides. Construction of operationally functional metal responsive fluorophores.炔烃与叠氮化物的1,3-偶极环加成反应。可操作的功能性金属响应荧光团的构建。

Chem Commun (Camb). 2008 May 21(19):2203-5. doi: 10.1039/b800284c. Epub 2008 Mar 28.

One-step construction of five successive rings by rhodium-catalyzed intermolecular double [2+2+2] cycloaddition: enantioenriched [9]helicene-like molecules.通过铑催化的分子间双[2+2+2]环加成一步构建五个连续环：对映体富集的类[9]螺旋烯分子。

Angew Chem Int Ed Engl. 2009;48(30):5470-3. doi: 10.1002/anie.200901962.

Catalytic "click" rotaxanes: a substoichiometric metal-template pathway to mechanically interlocked architectures.催化“点击”轮烷：通向机械互锁结构的亚化学计量金属模板途径。

J Am Chem Soc. 2006 Feb 22;128(7):2186-7. doi: 10.1021/ja056903f.

Tetra-2,3-pyrazinoporphyrazines with externally appended pyridine rings. 2. Metal complexes of tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazine: linear and nonlinear optical properties and electrochemical behavior.带有外部连接吡啶环的四-2,3-吡嗪并卟啉嗪。2. 四-2,3-[5,6-二(2-吡啶基)吡嗪]卟啉嗪的金属配合物：线性和非线性光学性质及电化学行为。

Inorg Chem. 2004 Dec 27;43(26):8637-48. doi: 10.1021/ic0489084.

A cycloaddition cascade approach to the total synthesis of (-)-FR182877.一种用于全合成(-)-FR182877的环加成串联方法。

J Am Chem Soc. 2003 Nov 5;125(44):13531-40. doi: 10.1021/ja037643+.

Cobalt-mediated two-carbon ring expansion of five-membered rings. Electrophilic carbon-carbon bond activation in the synthesis of seven-membered rings.钴介导的五元环的二碳环扩展。七元环合成中的亲电碳-碳键活化。

J Am Chem Soc. 2004 Aug 4;126(30):9184-5. doi: 10.1021/ja047852+.

Triplet acetylenes as synthetic equivalents of 1,2-bicarbenes, part II: new supramolecular scaffolds from photochemical cycloaddition of diarylacetylenes to 1,4-cyclohexadienes.作为1,2-双卡宾合成等效物的三联乙炔，第二部分：二芳基乙炔与1,4-环己二烯光化学环加成反应产生的新型超分子支架

Chemistry. 2005 Aug 19;11(17):4953-60. doi: 10.1002/chem.200500180.

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Construction of pyridine rings by metal-mediated [2 + 2 + 2] cycloaddition.

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