桥头芳基化：合成C-20二萜生物碱高级中间体的直接途径。
Bridgehead arylation: a direct route to advanced intermediates for the synthesis of C-20 diterpene alkaloids.
作者信息
Williams Craig M, Mander Lewis N
机构信息
Chemistry Department, School of Molecular and Microbial Sciences, University of Queensland, St. Lucia, 4072, Queensland, Australia.
出版信息
Org Lett. 2003 Sep 18;5(19):3499-502. doi: 10.1021/ol0353060.
PMID:12967309
Abstract
[reaction: see text] Rapid access to the ABCE ring system of the C(20) diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo[3.3.1]nonane derivative.
摘要
[反应：见正文] 通过银（I）促进的特定官能团5-溴-3-氮杂双环[3.3.1]壬烷衍生物的分子内傅克芳基化反应，可快速构建C(20)二萜生物碱的ABCE环系。
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