• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

在大气氧条件下新型钒催化醇氧化为醛和酮。

Novel vanadium-catalyzed oxidation of alcohols to aldehydes and ketones under atmospheric oxygen.

作者信息

Velusamy Subbarayan, Punniyamurthy T

机构信息

Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India.

出版信息

Org Lett. 2004 Jan 22;6(2):217-9. doi: 10.1021/ol036166x.

DOI:10.1021/ol036166x
PMID:14723532
Abstract

[reaction: see text] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using atmospheric oxygen and a catalytic amount of V2O5 in toluene under heating (ca. 100 degrees C). Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxy groups.

摘要

[反应：见正文] 已经研究了在加热（约100℃）下，使用大气中的氧气和催化量的五氧化二钒在甲苯中，将醇氧化为醛和酮，产率很高。仲醇在伯羟基存在下可化学选择性地转化为酮。

相似文献

1
Novel vanadium-catalyzed oxidation of alcohols to aldehydes and ketones under atmospheric oxygen.在大气氧条件下新型钒催化醇氧化为醛和酮。
Org Lett. 2004 Jan 22;6(2):217-9. doi: 10.1021/ol036166x.
2
Novel polyaniline-supported molybdenum-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.新型聚苯胺负载钼催化醇类有氧氧化为醛和酮
Org Lett. 2004 Dec 23;6(26):4821-4. doi: 10.1021/ol048195t.
3
TEMPO/HCl/NaNO2 catalyst: a transition-metal-free approach to efficient aerobic oxidation of alcohols to aldehydes and ketones under mild conditions.TEMPO/HCl/NaNO₂催化剂：一种在温和条件下将醇高效有氧氧化为醛和酮的无过渡金属方法。
Chemistry. 2008;14(9):2679-85. doi: 10.1002/chem.200701818.
4
Cytochrome P-450 model reactions: efficient and highly selective oxidation of alcohols with tetrabutylammonium peroxymonosulfate catalyzed by Mn-porphyrins.细胞色素P-450模型反应：锰卟啉催化过氧单硫酸四丁铵对醇的高效高选择性氧化反应
Bioorg Med Chem. 2007 Apr 15;15(8):3097-101. doi: 10.1016/j.bmc.2007.01.032. Epub 2007 Jan 20.
5
The direct catalytic asymmetric alpha-aminooxylation reaction: development of stereoselective routes to 1,2-diols and 1,2-amino alcohols and density functional calculations.直接催化不对称α-氨基氧基化反应：1,2-二醇和1,2-氨基醇立体选择性合成路线的开发及密度泛函计算
Chemistry. 2004 Aug 6;10(15):3673-84. doi: 10.1002/chem.200400137.
6
Selective aerobic oxidation of hydroxy compounds catalyzed by photoactivated ruthenium-salen complexes (selective catalytic aerobic oxidation).光活化钌-萨伦配合物催化的羟基化合物的选择性需氧氧化（选择性催化需氧氧化）
Chem Rec. 2004;4(2):96-109. doi: 10.1002/tcr.20001.
7
Novel Pd/C-catalyzed redox reactions between aliphatic secondary alcohols and ketones under hydrogenation conditions: application to H-D exchange reaction and the mechanistic study.新型钯/碳催化的脂肪族仲醇与酮在氢化条件下的氧化还原反应：在氢-氘交换反应中的应用及机理研究
J Org Chem. 2007 Mar 16;72(6):2143-50. doi: 10.1021/jo062582u. Epub 2007 Feb 22.
8
Homogeneous palladium catalyst suppressing Pd black formation in air oxidation of alcohols.在醇类的空气氧化中抑制钯黑形成的均相钯催化剂。
J Am Chem Soc. 2004 Jun 2;126(21):6554-5. doi: 10.1021/ja031936l.
9
Transition-metal- and organic-solvent-free: a highly efficient anaerobic process for selective oxidation of alcohols to aldehydes and ketones in water.无过渡金属和有机溶剂：一种在水中将醇选择性氧化为醛和酮的高效厌氧过程。
Org Biomol Chem. 2005 Oct 7;3(19):3473-5. doi: 10.1039/b509527a. Epub 2005 Sep 1.
10
A novel environmentally benign method for the selective oxidation of alcohols to aldehydes and ketones.一种将醇选择性氧化为醛和酮的新型环境友好方法。
Chem Asian J. 2007 Mar 5;2(3):411-5. doi: 10.1002/asia.200600383.

引用本文的文献

1
Aerobic oxidation catalyst vanadyl acetylacetonate boosts luminol chemiluminescence for sensitive detection of alkaline phosphatase and ascorbic acid.需氧氧化催化剂乙酰丙酮氧钒增强鲁米诺化学发光用于碱性磷酸酶和抗坏血酸的灵敏检测。
Anal Bioanal Chem. 2025 May;417(13):2879-2887. doi: 10.1007/s00216-025-05827-x. Epub 2025 Mar 17.
2
Organo-photocatalytic C-H bond oxidation: an operationally simple and scalable method to prepare ketones with ambient air.有机光催化碳氢键氧化：一种操作简单且可扩展的利用环境空气制备酮的方法。
RSC Adv. 2023 Mar 6;13(11):7168-7178. doi: 10.1039/d3ra00332a. eCollection 2023 Mar 1.
3
Mononuclear/Binuclear [VO]/[VO] Complexes Derived from 1,3-Diaminoguanidine and Their Catalytic Application for the Oxidation of Benzoin via Oxygen Atom Transfer.
源自1,3-二氨基胍的单核/双核[VO]/[VO]配合物及其通过氧原子转移催化安息香氧化的应用。
ACS Omega. 2022 Dec 16;8(1):1301-1318. doi: 10.1021/acsomega.2c06732. eCollection 2023 Jan 10.
4
On the Capability of Oxidovanadium(IV) Derivatives to Act as All-Around Catalytic Promoters Since the Prebiotic World.在原始生命世界中，氧化钒(IV)衍生物作为全方位催化促进剂的能力。
Molecules. 2020 Jul 6;25(13):3073. doi: 10.3390/molecules25133073.
5
Selective Oxidation of Biomass-Derived Alcohols and Aromatic and Aliphatic Alcohols to Aldehydes with O/Air Using a RuO-Supported MnO Catalyst.使用负载RuO的MnO催化剂将生物质衍生醇以及芳香族和脂肪族醇选择性氧化为醛类，以氧气/空气为氧化剂
ACS Omega. 2018 Jul 17;3(7):7944-7954. doi: 10.1021/acsomega.8b01009. eCollection 2018 Jul 31.
6
Heterogeneously Catalysed Oxidative Dehydrogenation of Menthol in a Fixed-Bed Reactor in the Gas Phase.固定床反应器中气相薄荷醇的多相催化氧化脱氢反应
ChemistryOpen. 2019 Jun 11;8(8):1066-1075. doi: 10.1002/open.201900158. eCollection 2019 Aug.
7
Novel Effect of Zinc Nitrate/Vanadyl Oxalate for Selective Catalytic Oxidation of α-Hydroxy Esters to α-Keto Esters with Molecular Oxygen: An In Situ ATR-IR Study.硝酸锌/草酰氧钒对α-羟基酯选择催化氧化为α-酮酯与分子氧的新型作用：原位 ATR-IR 研究。
Molecules. 2019 Apr 2;24(7):1281. doi: 10.3390/molecules24071281.
8
Tuning the Synthesis of Manganese Oxides Nanoparticles for Efficient Oxidation of Benzyl Alcohol.调控用于高效氧化苯甲醇的氧化锰纳米颗粒的合成
Nanoscale Res Lett. 2017 Dec;12(1):23. doi: 10.1186/s11671-016-1777-y. Epub 2017 Jan 6.
9
Non-oxidative vanadium-catalyzed C-O bond cleavage: application to degradation of lignin model compounds.非氧化钒催化的碳-氧键断裂：在木质素模型化合物降解中的应用
Angew Chem Int Ed Engl. 2010 May 17;49(22):3791-4. doi: 10.1002/anie.201001293.
10
Caste-specific tyramides from Myrmicine ants.兵蚁特有的酪胺衍生物。
J Nat Prod. 2010 Mar 26;73(3):313-6. doi: 10.1021/np900697s.