Lipowsky Gunter, Helmchen Günter
Organisch-Chemisches Institut der Ruprechts-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany.
Chem Commun (Camb). 2004 Jan 7(1):116-7. doi: 10.1039/b311502j. Epub 2003 Nov 7.
Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%.