铜催化二乙基锌对硝基烯烃的高度对映选择性共轭加成反应。
Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to nitroalkenes.
作者信息
Choi Hojae, Hua Zihao, Ojima Iwao
机构信息
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400.
出版信息
Org Lett. 2004 Aug 5;6(16):2689-91. doi: 10.1021/ol0491282.
PMID:15281745
Abstract
Copper-catalyzed asymmetric conjugate addition of diethylzinc to nitroalkenes using new chiral monodentate phosphoramidite ligands proceeds with high enantioselectivity up to 99% ee. [reaction: see text]
摘要
使用新型手性单齿亚磷酰胺配体，铜催化二乙基锌对硝基烯烃的不对称共轭加成反应具有高达99% ee的高对映选择性。[反应：见正文]
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