以邻苯二甲酸苄酯糖基化物作为新型糖基供体的糖基化反应。
Glycosylation with glycosyl benzyl phthalates as a new type of glycosyl donor.
作者信息
Kim Kwan Soo, Lee Yong Joo, Kim Hye Young, Kang Sung Soo, Kwon Soon Young
机构信息
Centre for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul, 120-749, Korea.
出版信息
Org Biomol Chem. 2004 Sep 7;2(17):2408-10. doi: 10.1039/b405793g. Epub 2004 Aug 4.
DOI:10.1039/b405793g
PMID:15326517
Abstract
A glucopyranosyl benzyl phthalate, two mannopyranosyl benzyl phthalates, and a 2-deoxyglucopyranosyl benzyl phthalate, which were prepared from the corresponding 1-hydroxy sugars and benzyl hydrogen phthalate, were found to be efficient glycosyl donors in the glycosylations of various glycosyl acceptors using TMSOTf as a promoter.
摘要
由相应的1-羟基糖和邻苯二甲酸苄酯制备得到的邻苯二甲酸苄基吡喃葡萄糖酯、两种邻苯二甲酸苄基吡喃甘露糖酯以及一种邻苯二甲酸苄基2-脱氧吡喃葡萄糖酯，在以三甲基甲磺酸镱（TMSOTf）作为促进剂的各种糖基受体的糖基化反应中被发现是有效的糖基供体。
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