糖基三氯乙酰氨基甲酸酯：一种用于O-糖基化的新型糖基供体。
Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation.
作者信息
Jayakanthan K, Vankar Yashwant D
机构信息
Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India.
出版信息
Carbohydr Res. 2005 Dec 12;340(17):2688-92. doi: 10.1016/j.carres.2005.07.024. Epub 2005 Oct 5.
PMID:16212950
Abstract
Glycosyl trichloroacetylcarbamates, readily obtained by reacting 1-hydroxy sugars with trichloroacetylisocyanate, have been found as excellent glycosyl donors, and the corresponding O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity.
摘要
糖基三氯乙酰氨基甲酸酯可通过1-羟基糖与三氯乙酰异氰酸酯反应轻松制得，已被发现是优异的糖基供体，相应的O-糖苷能以良好至优异的产率、相当高的选择性得以形成。
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