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β-环糊精对西维因测定中荧光的增敏作用。

Sensitized effect of beta-cyclodextrin on the fluorescence in the determination of carbaryl.

作者信息

Liu Wen-Li, Tang Bo

机构信息

College of Life Sciences and Medicine Chemical Engineering, Taizhou University, Taizhou 317000, China.

出版信息

J Environ Sci (China). 2004;16(5):829-31.

Abstract

Based on the significant enhancement of fluorescence intensity of carbaryl in inclusion complex, a spetrofluorimetric method with high sensitivity was developed for the determination of carbaryl in aqueous solution. Under the optimum conditions, the complex had excitation and emission maxima at 278 nm and 332 nm, respectively. The linear range of the method was 7.0 ng/ml-1500 ng/ml with a detection limit of 1.2 ng/ml. The proposed method was successfully used to determine quantitatively of carbaryl in cottonseeds.

摘要

基于西维因在包合物中荧光强度的显著增强,建立了一种高灵敏度的荧光分光光度法用于测定水溶液中的西维因。在最佳条件下,该配合物的激发和发射最大值分别为278nm和332nm。该方法的线性范围为7.0ng/ml - 1500ng/ml,检测限为1.2ng/ml。该方法成功用于定量测定棉籽中的西维因。

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