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常规生产和有机生产蔬菜中高亲脂性有机氯农药(OCP)残留量的评估。

Evaluation of conventionally and organically produced vegetables for high lipophilic organochlorine pesticide (OCP) residues.

作者信息

Gonzalez Mariana, Miglioranza Karina S B, Aizpún de Moreno Julia E, Moreno Víctor J

机构信息

Laboratorio de Ecotoxicología, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes 3350, 7600 Mar del Plata, Argentina.

出版信息

Food Chem Toxicol. 2005 Feb;43(2):261-9. doi: 10.1016/j.fct.2004.10.002.

Abstract

The occurrence and distribution of highly hydrophobic organochlorine pesticide (OCP) in vegetables cultivated under organic and conventional conditions were evaluated. OCP residues in aerial and subterranean tissues of two varieties of lettuce and chard together with the soil where they grown were GC-ECD analyzed. SigmaDDTs>SigmaChlordane>SigmaHeptachlor>SigmaAldrins was the OCP distribution pattern in all samples. Conventional soils had higher OCP residues than organic one, even though levels were bellow 5 ng/g dry weight, indicative of low polluted agricultural environments. Vegetables accumulated OCP efficiently with residue levels 4x to 45x fold greater than those of soils. OCP tissue-dependent distribution was found to be upon the physicochemical characteristics of the pollutants (Koa and Kow). Lettuce showed a high variability in pesticide uptake regarding varieties and tillage practices. In spite of analyzed pesticides are banned or restricted, edible tissues of vegetables from both farms showed detectable residues of these compounds even though at levels below the allowed by the Codex Alimentarius. Thus, environmental conditions like presence or absence of trees, hedgerows or nearby to conventional farms influence on OCP occurrence and levels in vegetables organically grown.

摘要

对在有机和传统条件下种植的蔬菜中高疏水性有机氯农药(OCP)的发生和分布进行了评估。对两个品种的生菜和甜菜的地上和地下组织以及它们生长的土壤中的OCP残留进行了气相色谱 - 电子捕获检测(GC - ECD)分析。所有样品中的OCP分布模式为:Σ滴滴涕>Σ氯丹>Σ七氯>Σ艾氏剂。传统土壤中的OCP残留量高于有机土壤,尽管含量低于5 ng/g干重,表明农业环境污染程度较低。蔬菜能够有效地积累OCP,其残留水平比土壤高4至45倍。发现OCP的组织依赖性分布取决于污染物的物理化学特性(Koa和Kow)。生菜在农药吸收方面因品种和耕作方式表现出很大的变异性。尽管所分析的农药已被禁止或限制使用,但两个农场蔬菜的可食用组织中均检测到这些化合物的残留,尽管其含量低于食品法典允许的水平。因此,诸如是否有树木、树篱或靠近传统农场等环境条件会影响有机种植蔬菜中OCP的发生和含量。

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