Noll James D, Timko Robert J, McWilliams Linda, Hall Peter, Haney Robert
Pittsburgh Research Center, National Institute for Occupational Safety and Health, Pittsburgh, Pennsylvania 15236, USA.
J Occup Environ Hyg. 2005 Jan;2(1):29-37. doi: 10.1080/15459620590900320.
Diesel particulate matter (DPM) samples from underground metal/nonmetal mines are collected on quartz fiber filters and measured for carbon content using National Institute for Occupational Safety and Health Method 5040. If size-selective samplers are not used to collect DPM in the presence of carbonaceous ore dust, both the ore dust and DPM will collect on the quartz filters, causing the carbon attributed to DPM to be artificially high. Because the DPM particle size is much smaller than that of mechanically generated mine dust aerosols, it can be separated from the larger mine dust aerosol by a single-stage impactor. The SKC DPM cassette is a single-stage impactor designed to collect only DPM aerosols in the presence of carbonaceous mine ore aerosols, which are commonly found in underground nonmetal mines. However, there is limited data on how efficiently the SKC DPM cassette can collect DPM in the presence of ore dust. In this study we investigated the ability of the SKC DPM cassette to collect DPM while segregating ore dust from the sample. We found that the SKC DPM cassette accurately collected DPM. In the presence of carbon-based ore aerosols having an average concentration of 8 mg/m3, no ore dust was detected on SKC DPM cassette filters. We did discover a problem: the surface areas of the DPM deposits on SKC DPM cassettes, manufactured prior to August 2002 were inconsistent. To correct this problem, SKC modified the cassette. The new cassette produced, with 99% confidence, a range of DPM deposit areas between 8.05 and 8.28 cm2, a difference of less than 3%.
地下金属/非金属矿山的柴油颗粒物(DPM)样本采集在石英纤维滤膜上,并按照美国国家职业安全与健康研究所的5040方法测量碳含量。如果在存在含碳矿尘的情况下未使用尺寸选择性采样器来采集DPM,那么矿尘和DPM都会收集在石英滤膜上,导致归因于DPM的碳含量被人为高估。由于DPM的粒径远小于机械产生的矿尘气溶胶,它可以通过单级冲击器与较大的矿尘气溶胶分离。SKC DPM采样盒是一种单级冲击器,设计用于在存在含碳矿矿石气溶胶(常见于地下非金属矿山)的情况下仅收集DPM气溶胶。然而,关于SKC DPM采样盒在存在矿尘的情况下收集DPM的效率的数据有限。在本研究中,我们调查了SKC DPM采样盒在从样本中分离矿尘的同时收集DPM的能力。我们发现SKC DPM采样盒能够准确收集DPM。在平均浓度为8毫克/立方米的碳基矿石气溶胶存在的情况下,在SKC DPM采样盒滤膜上未检测到矿尘。我们确实发现了一个问题:2002年8月之前生产的SKC DPM采样盒上DPM沉积物的表面积不一致。为纠正此问题,SKC对采样盒进行了改进。新生产的采样盒在99%的置信度下,DPM沉积面积范围在8.05至8.28平方厘米之间,差异小于3%。