自组装卟啉光子线的构建模块。

Building blocks for self-assembled porphyrinic photonic wires.

作者信息

Koepf M, Trabolsi A, Elhabiri M, Wytko J A, Paul D, Albrecht-Gary A M, Weiss J

机构信息

Laboratoire de Chimie des Ligands à Architecture Contrôlée, Institut de Chimie, Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.

出版信息

Org Lett. 2005 Mar 31;7(7):1279-82. doi: 10.1021/ol050033p.

DOI:10.1021/ol050033p

PMID:15787486

Abstract

[structure: see text] Based on the high affinity of phenanthroline-strapped porphyrins for imidazoles, building blocks for self-assembled, linear porphyrin architectures have been designed. Their synthesis is reported, and the assembly principle is illustrated by the formation of the shortest possible scaffold. Only one type of assembly is observed, and the stepwise energy transfer from the boron dipyrrylmethane (BODIPY) input to the free base output is highly efficient.

摘要

[结构：见正文] 基于菲咯啉连接的卟啉对咪唑的高亲和力，设计了用于自组装线性卟啉结构的构建模块。报道了它们的合成方法，并通过形成最短可能支架来说明组装原理。仅观察到一种组装类型，并且从硼二吡咯甲烷（BODIPY）输入到游离碱输出的逐步能量转移效率很高。