Córdova Armando, Engqvist Magnus, Ibrahem Ismail, Casas Jesús, Sundén Henrik
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Sweden.
Chem Commun (Camb). 2005 Apr 21(15):2047-9. doi: 10.1039/b500589b. Epub 2005 Mar 1.
The intrinsic ability of amino acids to catalyze the asymmetric formation of carbohydrates, which enzymes have mediated for millions of years, with significant amplification of enantiomeric excess suggests a plausible ancient catalytic process for the evolution of homochirality.
氨基酸催化碳水化合物不对称形成的内在能力,这种能力已由酶介导了数百万年,对映体过量有显著放大,这表明了一种关于同手性进化的看似合理的古老催化过程。