区域选择性路易斯酸介导的烯丙基乙烯基醚的[1,3]重排反应。
Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers.
作者信息
Nasveschuk Christopher G, Rovis Tomislav
机构信息
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
出版信息
Org Lett. 2005 May 26;7(11):2173-6. doi: 10.1021/ol0505151.
PMID:15901162
Abstract
[reaction: see text]. Aluminum and copper Lewis acids were implemented to effect a regioselective [1,3] rearrangement of allylvinyl ethers in moderate to good yields. The use of trisubstituted alkenes leads to depressed levels of Claisen products.
摘要
[反应：见正文]。采用铝和铜路易斯酸实现烯丙基乙烯基醚的区域选择性[1,3]重排，产率中等至良好。使用三取代烯烃会导致克莱森产物的产率降低。
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