Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids.
作者信息
Hoen Rob, Boogers Jeroen A F, Bernsmann Heiko, Minnaard Adriaan J, Meetsma Auke, Tiemersma-Wegman Theodora D, de Vries André H M, de Vries Johannes G, Feringa Ben L
机构信息
Department of Organic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
出版信息
Angew Chem Int Ed Engl. 2005 Jul 4;44(27):4209-12. doi: 10.1002/anie.200500784.
PMID:15929156
Abstract
摘要
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