Pérez-Madrid A
Departament de Física Fonamental, Facultat de Física, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
J Chem Phys. 2005 Jun 1;122(21):214914. doi: 10.1063/1.1925271.
The nonexponential relaxation and aging inherent to complex dynamics manifested in a wide variety of dissipative systems are analyzed through a model of diffusion in phase space in the presence of a nonconservative force. The action of this force establishes a heat flow which maintains the system away from equilibrium. The inability of the system to find its equilibrium state becomes apparent through the presence of an effective temperature field. This is the temperature of the stationary nonequilibrium state reached by the system satisfying a generalized version of the fluctuation-dissipation theorem. The presence of a nonequilibrium temperature leads to a hierarchy of relaxation times responsible for the aging phenomena and to a relation similar to the Vogel-Fulcher-Tammann law [H. Vogel, Phys. Z. 22, 645 (1921); G. S. Fulcher, J. Am. Ceram. Soc. 8, 339 (1925); 8, 789 (1925); G. Tammann and W. Hesse, Z. Anorg. Allg. Chem. 156, 245 (1926)].
通过一个在存在非保守力的相空间中扩散的模型,分析了各种耗散系统中复杂动力学所固有的非指数弛豫和老化现象。该力的作用建立了一个热流,使系统远离平衡态。通过有效温度场的存在,系统无法找到其平衡态变得明显。这是系统通过满足涨落耗散定理的广义版本而达到的稳态非平衡态的温度。非平衡温度的存在导致了负责老化现象的弛豫时间层次结构,并导致了与Vogel-Fulcher-Tammann定律类似的关系[H. Vogel, 《物理学报》22, 645 (1921); G. S. Fulcher, 《美国陶瓷学会杂志》8, 339 (1925); 8, 789 (1925); G. Tammann和W. Hesse, 《无机与普通化学杂志》156, 245 (1926)]。