一种高度水溶性的铂（II）配合物，其含有通过连接的甘油基团功能化的硫代丙基-1,2-二碳-闭式-十二硼烷（12）配体。
A highly water-soluble platinum(ii) complex containing a thiopropyl-1,2-dicarba-closo-dodecaborane(12) ligand functionalised with a pendant glycerol group.
作者信息
Crossley Ellen L, Caiazza Daniela, Rendina Louis M
机构信息
School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.
出版信息
Dalton Trans. 2005 Sep 7(17):2825-6. doi: 10.1039/b508020g. Epub 2005 Jul 20.
Reaction of the novel thiopropyl-closo-1,2-carborane ligand bearing a pendant glycerol group HS(CH(2))(3)CB(10)H(10)CCH(2)OCH(CH(2)OH)(2)(L) with the labile platinum(ii) precursor Pt(MeCN)(terpy)(2)(terpy = 2,2':6',2''-terpyridine; OTf = trifluoromethanesulfonate) affords the highly water-soluble platinum(ii) complex [PtL(terpy)]OTf, the first example of a metal-carborane complex functionalised with a water-solubilising glycerol group.
带有甘油侧基的新型硫代丙基-闭式-1,2-碳硼烷配体HS(CH₂)₃CB₁₀H₁₀CCH₂OCH(CH₂OH)₂（L）与不稳定的铂（II）前体Pt(MeCN)(terpy)₂（terpy = 2,2':6',2''-三联吡啶；OTf = 三氟甲磺酸盐）反应，得到了高度水溶性的铂（II）配合物[PtL(terpy)]OTf，这是首例用增溶甘油基团功能化的金属-碳硼烷配合物。
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