金属有机开放框架薄膜在Au(111)上图案化的COOH/CF₃端基自组装单分子层上的选择性成核与生长。
Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111).
作者信息
Hermes Stephan, Schröder Felicitas, Chelmowski Rolf, Wöll Christof, Fischer Roland A
机构信息
Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, D-44870 Bochum, Germany.
出版信息
J Am Chem Soc. 2005 Oct 12;127(40):13744-5. doi: 10.1021/ja053523l.
PMID:16201767
Abstract
Metal-Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.
摘要
金属有机开放框架配位聚合物（MOFs）是一类引人入胜的材料。我们展示了MOF-5图案化薄膜的选择性生长以及随后用钯有机化合物进行负载，该钯有机化合物作为在MOF-5材料腔内沉积钯纳米团簇的前体。
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