Zou Hua, Pan Gang, Chen Hao, Yuan Xianzheng
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
Environ Pollut. 2006 May;141(2):201-5. doi: 10.1016/j.envpol.2005.08.042. Epub 2005 Oct 5.
After sepiolite was modified with Fe3+ to increase its surface charge, the initial algal removal rate increased significantly, but its Q8h was not improved substantially at clay loadings below 0.1 g/L. Modification on netting and bridging properties of clays by either chitosan or polyacrylamide (PAM) dramatically increased flocculation (Q8h) of MA cells in freshwaters. Algal removal efficiencies of different solids, including Type III clays, local soils and sediments, were all improved to a similar level of >90% at a total loading of 0.011 g/L (contained 0.001 g/L chitosan) after they were modified with chitosan, making the idea of clearing up algal blooms using local soils/sediments possible. The mechanism of netting and bridging was confirmed to be the most important factor in improving the removal efficiency of cells, whereas clays also played important roles in the sedimentation of the floc.
用Fe3+对海泡石进行改性以增加其表面电荷后,初始藻类去除率显著提高,但在粘土负载量低于0.1 g/L时,其8小时去除量并未得到实质性改善。壳聚糖或聚丙烯酰胺(PAM)对粘土的网捕和架桥性能进行改性,显著提高了淡水中MA细胞的絮凝效果(8小时去除量)。包括III型粘土、当地土壤和沉积物在内的不同固体物质,在用壳聚糖改性后,在总负载量为0.011 g/L(含0.001 g/L壳聚糖)时,藻类去除效率均提高到了>90%的相似水平,这使得利用当地土壤/沉积物清除藻华成为可能。网捕和架桥机制被确认为提高细胞去除效率的最重要因素,而粘土在絮凝物的沉降中也起着重要作用。