Konstantinou Ioannis K, Hela Dimitra G, Albanis Triantafyllos A
Department of Chemistry, University of Ioannina, Ioannina 45110, Greece.
Environ Pollut. 2006 Jun;141(3):555-70. doi: 10.1016/j.envpol.2005.07.024. Epub 2005 Oct 14.
This review evaluates and summarizes the results of long-term research projects, monitoring programs and published papers concerning the pollution of surface waters (rivers and lakes) of Greece by pesticides. Pesticide classes mostly detected involve herbicides used extensively in corn, cotton and rice production, organophosphorus insecticides as well as the banned organochlorines insecticides due to their persistence in the aquatic environment. The compounds most frequently detected were atrazine, simazine, alachlor, metolachlor and trifluralin of the herbicides, diazinon, parathion methyl of the insecticides and lindane, endosulfan and aldrin of the organochlorine pesticides. Rivers were found to be more polluted than lakes. The detected concentrations of most pesticides follow a seasonal variation, with maximum values occurring during the late spring and summer period followed by a decrease during winter. Nationwide, in many cases the reported concentrations ranged in low ppb levels. However, elevated concentrations were recorded in areas of high pesticide use and intense agricultural practices. Generally, similar trends and levels of pesticides were found in Greek rivers compared to pesticide contamination in other European rivers. Monitoring of the Greek water resources for pesticide residues must continue, especially in agricultural regions, because the nationwide patterns of pesticide use are constantly changing. Moreover, emphasis should be placed on degradation products not sufficiently studied so far.
本综述评估并总结了有关希腊地表水(河流和湖泊)农药污染的长期研究项目、监测计划及已发表论文的结果。最常检测到的农药类别包括在玉米、棉花和水稻生产中广泛使用的除草剂、有机磷杀虫剂以及因在水生环境中具有持久性而被禁用的有机氯杀虫剂。最常检测到的化合物有除草剂中的莠去津、西玛津、甲草胺、异丙甲草胺和氟乐灵,杀虫剂中的二嗪农、甲基对硫磷,以及有机氯农药中的林丹、硫丹和艾氏剂。研究发现河流比湖泊污染更严重。大多数农药检测到的浓度呈现季节性变化,最大值出现在春末和夏季,随后在冬季下降。在全国范围内,许多情况下报告的浓度处于低ppb水平。然而,在农药使用量大和农业活动密集的地区记录到了较高浓度。总体而言,与其他欧洲河流的农药污染相比,希腊河流中农药的趋势和水平相似。必须继续监测希腊水资源中的农药残留,尤其是在农业地区,因为全国范围内的农药使用模式在不断变化。此外,应重点关注目前研究尚不充分的降解产物。