Shi H-M, Long B-S, Cui X-M, Min Z-D
Department of Natural Medicine Chemistry, China Pharmaceutical University, Nanjing 210009, China.
J Asian Nat Prod Res. 2005 Dec;7(6):857-60. doi: 10.1080/1028602042000204090.
The new sesquiterpenoid (6R)-2-chloro-6-[(1S)-1,5-dimethylhex-4-en-1-yl]-3-methylcyclohex-2-en-1-one (1), together with ten known compounds, (6R)-6-[(1S)-1,5-dimethylhex-4-en-1-yl]-3-methylcyclohex-2-en-1-one (2), bauerenol acetate (3), lupenone (4), alpha-amyrenone (5), beta-sitosterol (6), stigmasterol (7), beta-amyrin (8), ursolic acid (9), betulinic acid (10), scopolin (11), have been isolated from the roots of Euphorbia chrysocoma Lévl. et Vant. Their structures have been elucidated by spectroscopic data.
新的倍半萜类化合物(6R)-2-氯-6-[(1S)-1,5-二甲基己-4-烯-1-基]-3-甲基环己-2-烯-1-酮(1),与十种已知化合物,(6R)-6-[(1S)-1,5-二甲基己-4-烯-1-基]-3-甲基环己-2-烯-1-酮(2)、鲍尔烯醇乙酸酯(3)、羽扇豆酮(4)、α-香树脂酮(5)、β-谷甾醇(6)、豆甾醇(7)、β-香树脂醇(8)、熊果酸(9)、桦木酸(10)、东莨菪苷(11),已从大戟科植物金顶大戟的根中分离得到。它们的结构已通过光谱数据得以阐明。