Chen Hsiu-Ling, Shih Tung-Sheng, Huang Po-Chin, Hsieh Chia-Yi, Lee Ching-Chang
Department of Environmental and Occupational Health, Medical College, National Cheng Kung University, 138 Sheng-Li Road, Tainan 70428, Taiwan.
Chemosphere. 2006 Jul;64(4):666-71. doi: 10.1016/j.chemosphere.2005.10.059. Epub 2005 Dec 13.
This study aimed to evaluate serum polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) levels in electric-arc-furnace workers according to their corresponding occupational exposure. In addition, the ambient PCDD/Fs of the work environment were measured to provide additional support for the exposure and accumulation inside the electric arc furnace. The ambient PCDD/F concentrations inside the electric arc furnace were 1.557-1.917 pg-TEQ/Nm(3), 5-24 folds higher than those outside (0.080-0.385 pg-TEQ/N m(3)). In addition, higher average serum levels were measured in the workers with high occupational dioxin exposure (24.0 pg WHO-TEQ/g lipid) than in those with lower occupational dioxin exposure (13.8 pg WHO-TEQ/g lipid). Higher PCDFs/PCDDs ratios were found in serum samples from high-exposure groups than in low-exposure groups. The higher ratio of PCDFs/PCDDs was also found in ambient samples consistent with other metallurgical processes reported previously. Our results suggest that PCDD/Fs exposure exits in the smelting process of electric arc furnace, and the occupational hygiene should be taken more seriously concern in that workplace.
本研究旨在根据电弧炉工人相应的职业暴露情况,评估其血清中多氯二苯并对二噁英和二苯并呋喃(PCDD/Fs)的水平。此外,还测量了工作环境中的环境PCDD/Fs,为电弧炉内部的暴露和积累提供额外支持。电弧炉内的环境PCDD/F浓度为1.557 - 1.917 pg-TEQ/Nm(3),比外部(0.080 - 0.385 pg-TEQ/N m(3))高5 - 24倍。此外,职业性二噁英高暴露工人的血清平均水平(24.0 pg WHO-TEQ/g脂质)高于职业性二噁英低暴露工人(13.8 pg WHO-TEQ/g脂质)。高暴露组血清样本中的PCDFs/PCDDs比值高于低暴露组。在环境样本中也发现高暴露组的PCDFs/PCDDs比值更高,这与之前报道的其他冶金过程一致。我们的结果表明,电弧炉冶炼过程中存在PCDD/Fs暴露,该工作场所的职业卫生应受到更多关注。