Khlobystov Andrei N, Britz David A, Briggs G Andrew D
School of Chemistry, University of Nottingham, University Park, UK.
Acc Chem Res. 2005 Dec;38(12):901-9. doi: 10.1021/ar040287v.
This Account focuses on structural and dynamic behavior of molecules encapsulated in carbon nanotubes. The impact of the confinement on the molecular packing, orientation, translation, rotation, and reactivity is demonstrated for a range of fullerene and nonfullerene molecules. These phenomena are described and analyzed using the current understanding of molecule-nanotube and intermolecular interactions.
本综述聚焦于封装在碳纳米管中的分子的结构和动力学行为。对于一系列富勒烯和非富勒烯分子，展示了受限环境对分子堆积、取向、平移、旋转和反应性的影响。利用当前对分子 - 纳米管及分子间相互作用的理解来描述和分析这些现象。
