Zheng Ying, Yanful Ernest K, Bassi Amarjeet S
Department of Civil and Environmental Engineering, The University of Western Ontario, London, Ontario, Canada.
Crit Rev Biotechnol. 2005 Oct-Dec;25(4):243-50. doi: 10.1080/07388550500346359.
With more and more plastics being employed in human lives and increasing pressure being placed on capacities available for plastic waste disposal, the need for biodegradable plastics and biodegradation of plastic wastes has assumed increasing importance in the last few years. This review looks at the technological advancement made in the development of more easily biodegradable plastics and the biodegradation of conventional plastics by microorganisms. Additives, such as pro-oxidants and starch, are applied in synthetic materials to modify and make plastics biodegradable. Recent research has shown that thermoplastics derived from polyolefins, traditionally considered resistant to biodegradation in ambient environment, are biodegraded following photo-degradation and chemical degradation. Thermoset plastics, such as aliphatic polyester and polyester polyurethane, are easily attacked by microorganisms directly because of the potential hydrolytic cleavage of ester or urethane bonds in their structures. Some microorganisms have been isolated to utilize polyurethane as a sole source of carbon and nitrogen source. Aliphatic-aromatic copolyesters have active commercial applications because of their good mechanical properties and biodegradability. Reviewing published and ongoing studies on plastic biodegradation, this paper attempts to make conclusions on potentially viable methods to reduce impacts of plastic waste on the environment.
随着越来越多的塑料被应用于人类生活,以及塑料废物处理能力面临的压力不断增加,在过去几年中,对可生物降解塑料的需求以及塑料废物的生物降解变得越来越重要。本综述着眼于在开发更易生物降解塑料以及微生物对传统塑料的生物降解方面取得的技术进展。诸如促氧化剂和淀粉等添加剂被应用于合成材料中,以改性并使塑料具有生物可降解性。最近的研究表明,传统上被认为在环境中抗生物降解的聚烯烃衍生热塑性塑料,在光降解和化学降解后会发生生物降解。热固性塑料,如脂肪族聚酯和聚酯型聚氨酯,由于其结构中酯键或脲键潜在的水解断裂,很容易被微生物直接攻击。一些微生物已被分离出来,能够将聚氨酯作为唯一的碳源和氮源加以利用。脂肪族 - 芳香族共聚酯因其良好的机械性能和生物可降解性而具有积极的商业应用。通过回顾已发表的以及正在进行的关于塑料生物降解的研究,本文试图就减少塑料废物对环境影响的潜在可行方法得出结论。