在需氧和厌氧条件下，红平红球菌对甲基壬酸酯的拆分。
Resolution of methyl nonactate by Rhodococcus erythropolis under aerobic and anaerobic conditions.
作者信息
Nikodinovic Jasmina, Dinges Jennifer M, Bergmeier Stephen C, McMills Mark C, Wright Dennis L, Priestley Nigel D
机构信息
Department of Chemistry, University of Montana, Missoula, Montana 59812, USA.
出版信息
Org Lett. 2006 Feb 2;8(3):443-5. doi: 10.1021/ol052739p.
PMID:16435855
Abstract
[reaction: see text]. An efficient resolution of methyl nonactate is reported by biotransformation in shake flask cultures of Rhodococcus erythropolis. The equilibrium of the reaction redox system can be manipulated by switching from aerobic to anaerobic growth, thereby generating both enantiomers of the target in excellent yield and enantiomeric purity.
摘要
[反应：见正文]。报道了在红平红球菌摇瓶培养物中通过生物转化对壬酸甲酯进行有效拆分。通过从需氧生长转换为厌氧生长，可以控制反应氧化还原系统的平衡，从而以优异的产率和对映体纯度生成目标物的两种对映体。
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