亲核N-杂环卡宾催化醛的氰基磷酸化反应。
Cyano-phosphorylation of aldehydes catalyzed by a nucleophilic N-heterocyclic carbene.
作者信息
Fukuda Yoshimasa, Maeda Yuka, Kondo Kazuhiro, Aoyama Toyohiko
机构信息
Graduate School of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2006 Mar;54(3):397-8. doi: 10.1248/cpb.54.397.
PMID:16508201
Abstract
The first method for cyano-phosphorylation of aldehydes with diethyl cyanophosphonate in the presence of N-heterocyclic carbene prepared from 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride and KOt-Bu, as a nucleophilic catalyst, is described.
摘要
描述了在由1,3-双（2,4,6-三甲基苯基）咪唑鎓氯化物和叔丁醇钾制备的N-杂环卡宾作为亲核催化剂存在下，用氰基磷酸二乙酯对醛进行氰基磷酸化的第一种方法。
Zotero 插件