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生命起源的化学:从碳质陨石角度看

The chemistry of life's origin: a carbonaceous meteorite perspective.

作者信息

Pizzarello Sandra

机构信息

Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604, USA.

出版信息

Acc Chem Res. 2006 Apr;39(4):231-7. doi: 10.1021/ar050049f.

Abstract

Carbonaceous chondrite meteorites are primitive asteroidal fragments that contain organic carbon and offer a glimpse of the abiotic chemical processes that preceded the onset of life. Their organic material displays structures as diverse as kerogen-like macromolecules and simpler soluble compounds that range from polar amino acids and polyols to nonpolar hydrocarbons. Several of these compounds have identical counterparts in terrestrial biomolecules and some of the amino acids show a unique l-asymmetry, suggesting their possible contribution to terrestrial molecular evolution and the origin of biological homochirality.

摘要

碳质球粒陨石是原始的小行星碎片,含有有机碳,让我们得以一窥生命起源之前的非生物化学过程。它们的有机物质呈现出多样的结构,从类干酪根大分子到更简单的可溶性化合物,范围从极性氨基酸和多元醇到非极性碳氢化合物。其中几种化合物在陆地生物分子中有相同的对应物,一些氨基酸表现出独特的L-不对称性,这表明它们可能对陆地分子进化和生物同手性的起源有贡献。

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