豪胺A和B的3-氮杂-[7]-对环芳烷核心的合成。
Synthesis of the 3-aza-[7]-paracyclophane core of haouamine A and B.
作者信息
Wipf Peter, Furegati Markus
机构信息
Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA. pwipf+@pitt.edu
出版信息
Org Lett. 2006 Apr 27;8(9):1901-4. doi: 10.1021/ol060455e.
PMID:16623580
Abstract
[reaction: see text] The synthesis of the highly strained 3-aza-[7]-paracyclophane core of haouamines A and B is based on a macrocyclization-aromatization protocol, allowing for a stepwise increase in ring strain and establishing the oxygenation pattern of the natural products.
摘要
[反应：见正文] 哈乌胺A和B的高度张力3-氮杂-[7]-对环芳烷核心的合成基于大环化-芳构化方案，可逐步增加环张力并确定天然产物的氧化模式。
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