Bajwa Naval, Jennings Michael P
Department of Chemistry, University of Alabama, 500 Campus Drive, Tuscaloosa, Alabama 35487-0336, USA.
J Org Chem. 2006 Apr 28;71(9):3646-9. doi: 10.1021/jo0601664.
Two complementary procedures have been developed that selectively allow for the synthesis of either substituted salicylaldehydes or the corresponding 2-hydroxylbenzyl alcohols upon treatment of the 2,2-dimethyl-1,3-benzodioxan-4-one functional group with DIBAL-H or LAH, respectively.
已经开发出两种互补的方法，分别用二异丁基氢化铝（DIBAL-H）或氢化铝锂（LAH）处理2,2-二甲基-1,3-苯并二恶烷-4-酮官能团时，能够选择性地合成取代水杨醛或相应的2-羟基苄醇。
