2-氮杂金刚烷N-氧基（AZADO）和1-甲基-AZADO：用于醇氧化的高效有机催化剂。
2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO: highly efficient organocatalysts for oxidation of alcohols.
作者信息
Shibuya Masatoshi, Tomizawa Masaki, Suzuki Iwao, Iwabuchi Yoshiharu
机构信息
Department of Organic Chemistry and Biophysical Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Sendai 980-8578, Japan.
出版信息
J Am Chem Soc. 2006 Jul 5;128(26):8412-3. doi: 10.1021/ja0620336.
PMID:16802802
Abstract
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl compounds in excellent yields.
摘要
本文描述了用于高效氧化醇类的稳定氮氧自由基类催化剂2-氮杂金刚烷N-氧基（AZADO）和1-甲基-AZADO的开发。AZADO和1-甲基-AZADO表现出优于TEMPO的催化能力，能以优异的产率将各种位阻醇转化为相应的羰基化合物。
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