通过Mg(ClO4)2或分子碘催化的三组分反应合成α-氨基膦酸酯的简便高效方法。
A facile and highly efficient route to alpha-amino phosphonates via three-component reactions catalyzed by Mg(ClO4)2 or molecular iodine.
作者信息
Wu Jie, Sun Wei, Xia Hong-Guang, Sun Xiaoyu
机构信息
Department of Chemistry, Fudan University, Shanghai, China.
出版信息
Org Biomol Chem. 2006 May 7;4(9):1663-6. doi: 10.1039/b602536f. Epub 2006 Mar 28.
DOI:10.1039/b602536f
PMID:16633557
Abstract
Three-component reactions of aldehydes, amines, and diethyl phosphite catalyzed by Mg(ClO4)2 or molecular iodine afforded the corresponding alpha-amino phosphonates in excellent yields under mild reaction conditions.
摘要
在温和的反应条件下，由高氯酸镁或分子碘催化的醛、胺和亚磷酸二乙酯的三组分反应能以优异的产率得到相应的α-氨基膦酸酯。
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