(+)-SCH 351448的对映选择性全合成
Enantioselective total synthesis of (+)-SCH 351448.
作者信息
Crimmins Michael T, Vanier Grace S
机构信息
Venable and Kenan Laboratories of Chemistry, University of North Carolina at Chapel Hill, 27599, USA.
出版信息
Org Lett. 2006 Jun 22;8(13):2887-90. doi: 10.1021/ol061073b.
PMID:16774282
Abstract
[structure: see text] A stereoselective synthesis of SCH 351448 has been completed. Twelve of the fourteen stereogenic centers were established through chiral enolate reactions, and six key C-C bonds were formed by metathesis reactions.
摘要
[结构：见正文] SCH 351448的立体选择性合成已完成。14个立体中心中的12个通过手性烯醇盐反应构建，6个关键的碳-碳键通过复分解反应形成。
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