Keck Gary E, Welch Dennie S, Vivian Paige K
Department of Chemistry, University of Utah, 315 South 1400 East RM 2020, Salt Lake City, Utah 84112-0850, USA.
Org Lett. 2006 Aug 17;8(17):3667-70. doi: 10.1021/ol061173h.
[reaction: see text] The synthesis of a C1-C13 A-ring subunit of bryostatin 1 is detailed. The key features of the approach include the convergent fragment assembly with a highly stereoselective construction of the C7-C8 bond indicated above.
[反应:见正文] 详细介绍了苔藓抑素1的C1 - C13 A环亚基的合成。该方法的关键特征包括片段汇聚组装以及上述C7 - C8键的高度立体选择性构建。