da Silva Nivea de Lima, Maciel Maria Regina Wolf, Batistella César Benedito, Maciel Filho Rubens
Laboratory of Separation Process Development (LDPS), School of Chemical Engineering, State University of Campinas, São Paulo, Brazil, CP 6066, CEP 13081-970.
Appl Biochem Biotechnol. 2006 Spring;129-132:405-14. doi: 10.1385/abab:130:1:405.
The transesterification of castor oil with ethanol in the presence of sodium ethoxide as catalyst is an exceptional option for the Brazilian biodiesel production, because the castor nut is quite available in the country. Chemically, its oil contains about 90% of ricinoleic acid that gives to the oil some beneficial characteristics such as its alcohol solubility at 30 degrees C. The transesterification variables studied in this work were reaction temperature, catalyst concentration and alcohol oil molar ratio. Through a star configuration experimental design with central points, this study shows that it is possible to achieve the same conversion of esters carrying out the transesterification reaction with a smaller alcohol quantity, and a new methodology was developed to obtain high purity biodiesel.
在乙醇钠作为催化剂的存在下,蓖麻油与乙醇进行酯交换反应是巴西生物柴油生产的一个特殊选择,因为该国蓖麻籽资源丰富。从化学角度来看,其油中含有约90%的蓖麻油酸,这赋予了该油一些有益特性,比如在30摄氏度时可溶于醇。本研究中所考察的酯交换反应变量包括反应温度、催化剂浓度和醇油摩尔比。通过带有中心点的星型配置实验设计,本研究表明,使用较少量的醇进行酯交换反应也能够实现相同的酯转化率,并且开发了一种新方法来获得高纯度生物柴油。