Varala Ravi, Nuvula Sreelatha, Adapa Srinivas R
Indian Institute of Chemical Technology, Hyderabad-500 007, India.
J Org Chem. 2006 Oct 13;71(21):8283-6. doi: 10.1021/jo0612473.
An efficient and practical protocol for the protection of various structurally and electronically divergent aryl and aliphatic amines using (Boc)2O in the presence of a catalytic amount of molecular iodine (10 mol %) under solvent-free conditions at ambient temperature is presented.
本文提出了一种高效实用的方案,即在无溶剂条件下,于室温下,使用催化量的分子碘(10 mol%),以二碳酸二叔丁酯((Boc)2O)保护各种结构和电子性质不同的芳胺和脂肪胺。