Wang Shaozhong, Zhang Liming
Department of Chemistry/216, University of Nevada, Reno, 1664 North Virginia Street, Reno, Nevada 89557, USA.
J Am Chem Soc. 2006 Nov 8;128(44):14274-5. doi: 10.1021/ja066220f.
A novel Au-catalyzed migratory cycloisomerization strategy is advanced. Implementation of this strategy led to the development of a unique Au-catalyzed 1,5-enyne cycloisomerizatioin involving carboxy migration and Au-mediated C-C single bond formation. 1-Carboxycyclohexa-1,4-dienes and carboxyarenes can be prepared with good efficiency and with flexible substitution patterns.
一种新型的金催化迁移环异构化策略被提出。该策略的实施导致了一种独特的金催化1,5-烯炔环异构化反应的发展，该反应涉及羧基迁移和金介导的碳-碳单键形成。1-羧基环己-1,4-二烯和羧基芳烃能够以良好的效率和灵活的取代模式制备。
