Hisham A, John Shaly, Al-Shuaily Wafa, Asai Teigo, Fujimoto Yoshinori
Department of Chemistry, College of Science, Sultan Qaboos University, P.O. Box-36, Al-Khode-123, Oman.
Nat Prod Res. 2006 Oct;20(12):1046-52. doi: 10.1080/14786410500399714.
Chemical investigation of the leaves of Tephrosia apollinea has yielded a new flavanone named (+)-apollineanin, together with two known flavones: (-)-semiglabrin and (-)-semiglabrinol. The structure of the new compound was determined on the basis of mass, 1D and 2D NMR spectroscopies including NOE difference spectroscopy. The absolute stereochemistry of (+)-apollineanin was determined by Mosher ester methodology and from CD data.
对紫穗槐叶进行化学研究，得到了一种名为(+)-紫穗槐宁的新黄烷酮，以及两种已知黄酮：(-)-半光荚豆素和(-)-半光荚豆醇。通过质谱、一维和二维核磁共振光谱（包括NOE差光谱）确定了新化合物的结构。通过莫舍尔酯法和圆二色光谱数据确定了(+)-紫穗槐宁的绝对立体化学结构。
