用于中红外成像应用的亲脂性 Re(CO)pyca 配合物。
Lipophilic Re(CO)pyca complexes for Mid-IR imaging applications.
机构信息
Department of Chemistry, University of Akron, Akron, Ohio 44312-3601, USA.
Department of Chemistry, College of Wooster, Wooster, Ohio 44691, USA.
出版信息
Dalton Trans. 2021 Jan 27;50(3):1069-1075. doi: 10.1039/d0dt03743e.
Abstract
Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.
摘要
已经通过一锅法合成了几种含有长脂肪胺的 Re(i)pyca 缀合物。这些化合物已经得到了充分的表征，其中七种化合物通过单晶 X 射线衍射得到了结构解析。C14 变体被探索为一种潜在的有机金属 IR 染料。用 DOPC 和 C14 化合物生成了大单室囊泡，我们通过 FTIR 显微镜观察到铼配合物的掺入。
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