Gota Chie, Uchiyama Seiichi, Ohwada Tomohiko
Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Analyst. 2007 Feb;132(2):121-6. doi: 10.1039/b615168j. Epub 2006 Dec 18.
Fluorescent polymeric thermometers consisting of only N-alkylacrylamide and fluorescent components show rather low temperature resolution in their functional ranges (ca. 15-50 degrees C) because of the occurrence of intermolecular aggregation, which causes hysteresis in their fluorescence response to changes in temperature. By adding an ionic component to prevent such intermolecular aggregation, we obtained four fluorescent polymeric thermometers that offer high temperature resolution (<0.2 degrees C). Each new fluorescent polymeric thermometer covered the temperature range, 9-33 degrees C, 30-51 degrees C, 49-66 degrees C or 4-38 degrees C.
仅由N-烷基丙烯酰胺和荧光成分组成的荧光聚合物温度计在其功能范围内(约15-50摄氏度)显示出相当低的温度分辨率,这是由于分子间聚集的发生,导致其对温度变化的荧光响应出现滞后现象。通过添加离子成分来防止这种分子间聚集,我们获得了四种具有高温度分辨率(<0.2摄氏度)的荧光聚合物温度计。每种新型荧光聚合物温度计覆盖的温度范围为9-33摄氏度、30-51摄氏度、49-66摄氏度或4-38摄氏度。